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Cape Tuesday

The second set of images are, in alphabetical order, various types of people that can be paired with images in the first set to form superheroes. Using the number from the person image to index into the images from the first set in order yields:

SuperheroIndexLetter
WONDER Woman3N
HELL Boy2E
SPIDER Man3I
SCARLET Witch5L
STAR Lord3A
Captain AMERICA4R
Doctor MANHATTAN1M
SQUIRREL Girl1S
NIGHT Crawler5T
Mister FREEZE2R
Human TORCH2O
King PIN3N
GHOST Rider1G

The answer is therefore NEIL ARMSTRONG.